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Thesis Name: |
Research advance in catalyst of synthesis of |
Usage: |
catalyst |
Keyword: |
123 |
Remarks: |
Research advance in catalyst of synthesis of
2-methyl-2-ethoxycarbonylmethyl-1,3-dioxolane-B
LU Bao-lan,YANG Shui-jin
(Department of Chemistry and Environmental Engineering,Hubei Normal University, Huangshi 435002, China)
Abstract:The experiment result of Al2(SO4)3 , anhydrousAlCl3 、FeCl3、CuCl2、ZnCl2,solid super acid SO2-4/ZrO2、SO2-4/TiO2、SO2-4/TiO2-La2O3、SO2-4/TiO2-MoO3、SO2-4/TiO2-WO3, solid supported heteropoly acids,H3PW12O40/PAn,TiSiW12O40/TiO2, HY type molecular sieve and FeCl3-AlCl3-UR, about ten kinds of catalysts catalytic synthesize 2-methyl-2-ethoxycarbonylmethyl-1,3-dioxolane-B was presented. It showed that Al2(SO4)3, solid super acid SO2-4/TiO2-La2O3、SO2-4/TiO2-WO3, actived carbon supported heteropoly acids and FeCl3-AlCl3-UR have high yield for 2-methyl-2-ethoxycarbonyl-methyl-1,3-dioxolane-B, and also have actual application value.
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