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Thesis Name: |
Modification effect of cerium in gas hydrogenation of acrylonitrile over Pd/Al2O3 catalysts |
Usage: |
Ceria exhibits very interesting properties as prom |
Keyword: |
Hydrogenation; Acrylonitrile; Cerium |
Remarks: |
Low-loaded Pd (0.05 wt.%)/Al2O3 catalysts doped with cerium were prepared by wet impregnation method, then calcined and reduced by H2 at 773K. Selective gas phase hydrogenation of acrylonitrile over as-prepared catalysts was carried out in fixed bed reactor. The investigation indicated that the selectivity of hydrogenation of acrylonitrile to propionitrile over all the as-prepared catalysts was nearly 100%. And the addition of cerium improved the activity and stability greatly compared with Pd/Al2O3 sample studied as reference. All these may be due to the "electronic and structural effect" according to various characterizations。 |
Original file: |
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Promulgator Detail |
Full name: |
hichem |
Country: |
CN |
City: |
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Company Name: |
hichem |
Homepage: |
http://www.teloon.com |
E-mail: |
reply |
Phone: |
86-411-82819585 |
Fax: |
86-411-82819612 |
Company Address: |
Renming Road, Dalian city, Lianning pro,china |
Zip/Postal Code: |
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