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Thesis Name: Novel red phosphors for solid-state lighting: the system NaM(WO4)2−x(MoO4)x:Eu3+ (M=Gd, Y, Bi)
Usage: Novel red phosphors
Keyword: Novel red phosphors
Remarks: Solid solutions of tungstate and molybdate scheelites of formula NaLn(WO4)2−x(MoO4)x and NaY1−yBiy(WO4)2 (Ln = Y, Gd) doped with Eu3+ ion have been synthesized by solid-state reactions. Red luminescence is obtained in these samples on excitation either in the charge-transfer band or Eu3+ levels. In particular, intense red emission is obtained by exciting at ~394 nm using the sharp 7F0→5L6 line of Eu3+. These materials could find applications as red phosphors for white lighting devices utilizing GaN-based excitation in the near UV.
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