| Name: |
The Concept of Micellar-Sponge Nanophases in Chemi |
| ISBN: |
90-6764-402-1 |
| Language Version: |
english |
| Author: |
Yu.A. Mikheev and G.E. Zaikov |
| PUBLISHER: |
Brill Academic Publishers. |
| Pages: |
440 |
| Publishing Date: |
2004-01-01 |
| Contents: |
This monograph is intended for elucidation of the novel trend in chemical physics regarding the polymer non-crystalline phase. It stresses the physical phenomena affecting the kinetics and mechanism of chemical reactions proceeding in the non-crystalline polymer matrix (NCPM). NCPM is depicted in terms of a supramolecular (carcass-micellar) model. The model is thought to reflect heterophase packing of polymeric chains, which co-operate as a molecular-chain sponge.
The NCPM model presented is proved for adequate description of principal structure-physical phenomena to elaborate the scheme of structural-kinetic modeling of chemical reactions in bulky polymers. Structure-physical phenomena elucidated in the monograph are:
-- peculiarities of polymer plasticization and polymer blending with liquids;
-- structural and thermodynamic aspects of sorption of low molecular species;
-- properties of ESR (spin) probes and optical (molecular) probes;
-- features of water absorbed by polymers;
-- mechanical and thermal effects generated by the molecular-chain sponge;
-- supramolecular aspects of NCPM chemical physics. |
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| Promulgator Detail |
| Full name: |
hichem |
| Country: |
CN |
| City: |
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| Company Name: |
hichem |
| Homepage: |
http://www.teloon.com |
| E-mail: |
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86-411-82819585 |
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